课程教学
本科生课程:《环境健康危害与防护》、《学科竞赛能力训练》
研究生课程:《水化学理论与应用》
实践教学:指导本科毕业设计、创新创业比赛、创新实验、学科竞赛等
学生培养
坚持立德树人根本任务,精心指导本科生和研究生的培养,通过科教育人、产教育人、竞教育人,注重全面培养学生的综合素质,因材施教,多名研究生数次获得市级(校级)优秀毕业生和国家奖学金。连续三年指导研究生入选上海市研究生创新创业能力培养专项、连续多年指导的研究生均获得国家奖学金等奖项。多人次获得学术之星、学术先锋、学术达人等重要奖项。指导本科生连续五年获得国家级大学生创新计划和上海市大学生创新计划。
担任4166am官网登录新生院本科生导师和环境科学创新实验区导师,获得4166am官网登录教学成果奖特等奖、4166am官网登录本科生学科竞赛优秀指导教师。担任环境工程硕士研究生班主任,获得4166am官网登录先进班集体、优秀班主任、4166am官网登录优秀党员等荣誉称号。
坚持科教育人,指导学生参加挑战杯大学生创新创业、课外科技作品等科创比赛,多次获得重要奖项,包括:
第十七届“挑战杯”全国大学生课外学术科技作品竞赛选拔赛特等奖
第八届“挑战杯”中国大学生创业计划竞赛选拔赛一等奖
第十二届“挑战杯”中国大学生创业计划竞赛选拔赛金奖
第十二届“挑战杯”中国大学生创业计划竞赛上海市银奖
第八届“挑战杯”中国大学生创业计划竞赛上海市铜奖
第十七届“挑战杯”全国大学生课外学术科技作品竞赛上海市三等奖
第九届“上汽教育杯”上海市高校学生科技创新作品二等奖
第三届中国“互联网+”生态环境创新创业大赛优秀奖
第十六届全国环境友好科技竞赛一等奖2项(全国4项)
上海市发明协会“科技创业杯”三等奖、协鑫杯实践大赛二等奖、虹口区创客大赛一等奖等。
指导研究生参加新型城镇化全国大型暑期社会实践,获得团中央优秀社会实践团体二等奖。
科研工作
围绕多介质环境污染物转化与效应,开展了污染物毒性削减与定向转化、亚铁矿物驱动的污染物净化和环境修复机制、类Fenton以及活化过硫酸盐等高级氧化反应机制、催化氧化深度处理PPCPs等新兴污染物、FCDI分离回收原理与技术等关键内容研究。注重实验室基础研究与现场工程应用研究相结合,以技术需求为导向,攻克复杂地质中环境污染修复、废水深度处理与回用等多项技术难题,推动了技术成果转化和工程应用。
主持国家重点研发计划(项目首席)、国家自然科学基金(5项)、国家科技支撑计划等国家和省部级重要科研项目以及企业委托项目20多项。在Environ. Sci. Technol., Appl. Catal., B., Water Res.在等国内外学术期刊发表论文将110多篇,其中SCI/EI收录论文90多篇,ESI高被引论文4篇,获得授权发明专利近30项,多项专利技术实施转让,实现重大工程应用,获得省部级科技奖励一等奖2项。
获得国家科学技术学术著作出版基金资助,出版学术专著《结合态亚铁与污染物反应原理及其应用》。
担任国家自然科学基金委通讯评议专家、国家中长期科技发展规划纲要评估专家、国家十三五技术专家库专家、国家人才计划评审专家、教育部学位中心评审专家、奥克兰大学博士学位论文海外评阅人、Environ. Sci. Technol., Water Res.等多个国内外期刊审稿人。国际水协会(IWA)高级会员、《工业水处理》编委、《中国化学快报》编委、《中国化学快报》编委、《Environmental Functional Materials》创刊编委、化工学会工业水处理专委会委员、城市环境卫生协会专家委员。
科研项目
1.国家重点研发计划项目,“农村厕所粪便高效资源化处理关键技术与示范(****1903200)”,项目负责人(首席)
2.国家重点研发计划项目,“支撑重大环保设施高质高效运营的关键技术标准研究及应用(****0213203)”,课题任务负责人
3.国家重点研发计划项目,“农村厕所污染物深度控制与资源化利用关键技术与装备(****1903202)”,课题负责人
4.国家自然科学基金面上项目,“重金属与有机物同步去除过程中催化剂原位生成及活化分子氧机制(****6223)”,项目负责人
5.国家自然科学基金面上项目,“羧基配体促进黄铁矿-水异质微界面高活性氧化物种的形成机制及去除PPCPs研究(****2210)”,项目负责人
6.国家自然科学基金面上项目,“还原破络与臭氧耦合处理金属络合废水过程高活性氧化物种的生成调控与定向氧化机制”(****0091),项目负责人
7.国家自然科学基金面上项目,“纳米铁壳层物种反应活性及原位矿物转化同步除砷机制(****2211)”,项目负责人
8.国家自然科学基金青年基金,“Fe0-H2O界面多羟基铁类化合物的异常活性及老化过程和调控机理研究(****8136)”, 项目负责人
9.中央高校基本科研业务费,“地下水中重金属的迁移模拟及去除技术”,项目负责人
10.十二五国家科技支撑计划,“田园社区型乡村生活污染综合治理技术与示范”,课题负责人
11. 上海建科环境委托项目,“铁基缓释材料修复地下水环境中氯代烃类污染物研发与技术服务”,课题负责人
12.上海市崇明区委托项目,“畜禽养殖区周边水环境承载力分析及工程措施方案研究”,项目负责人
13.普莱克斯(中国)投资有限公司资助项目,“非均相催化臭氧氧化深度处理印染废水研究”,项目负责人
14.上海市环境工程设计科学研究院有限公司委托项目,“ISO30500国际标准环境指标体系及测试方法对标研究”,项目负责人
15.上海市崇明区委托项目,“崇明区水质断面溯源分析研究及其信息管理系统项目”,项目负责人
16.宝山钢铁股份有限公司委托项目,“冷轧含铬废水重金属捕集技术开发研究”,项目负责人
17.绍兴江滨水处理有限公司委托项目,“合作共建滨海印染产业集聚区水处理技术研发基地”,项目负责人
18.上海市测绘院委托项目,“崇明区第二次全国污染源普查项目”,项目负责人
19.河北雄安迈嵘环保科技公司委托项目,“全循环生态厕所系统开发与产品设计”,项目负责人
20.国家高技术发展研究计划“863”重点项目,“催化还原处理技术与装置研究”,(****063902),主要完成人
21.国家十二五科技支撑计划重大项目,“铁基复合水处理材料开发与应用”(****AC01B01),主要完成人
22.国家科技支撑计划,“村镇住宅污染物处置排放技术标准模式集成与示范研究”,(****J08B21),主要完成人
23.教育部重大科技项目,“精细化工废水生物强化处理成套技术开发,(****142)”,主要完成人
24.美国地质调查局项目,“Factors Controlling DDE Dechlorination Rates on the Palos Verdes Shelf: A Field and Laboratory Investigation”,主要完成人
部分论文
1.Zong, Yang; Shao, Yunfei; Zeng, Yunqiao; Shao, Binbin; Xu, Longqian; Zhao, Zhenyu; Liu, Wen;Wu, Deli. Enhanced Oxidation of Organic Contaminants by Iron(II)-Activated Periodate: The Significance of High-Valent Iron−Oxo Species,Environmental Science & Technology 2021 55 (11), 7634-7642(Supplementary Cover Article)
2.Longqian Xu, Yunfeng Mao, Yang Zong, Shuai Peng, Xiaomeng Zhang, andDeli Wu, Membrane-Current Collector-Based Flow-Electrode Capacitive Deionization System: A Novel Stack Configuration for Scale-Up Desalination,Environmental Science & Technology 2021 55 (19), 13286-13296
3.Yang Zong, Xiaohong Guan, Jun Xu, Yong Feng, Yunfeng Mao, Longqian Xu, Huaqiang Chu, andDeli Wu, Unraveling the Overlooked Involvement of High-Valent Cobalt-Oxo Species Generated from the Cobalt(II)-Activated Peroxymonosulfate Process,Environmental Science & Technology 2020 54 (24), 16231-16239
4.Qianyuan Yang, Longqian Xu, Qunbiao He,Deli Wu, Reduced cathodic scale and enhanced electrochemical precipitation of Ca2+ and Mg2+ by a novel fenced cathode structure: Formation of strong alkaline microenvironment and favorable crystallization,Water Research, 209, 2022, 117893
5.Longqian Xu, Ren Ding, Yunfeng Mao, Shuai Peng, Zheng Li, Yang Zong,Deli Wu, Selective recovery of phosphorus and urea from fresh human urine using a liquid membrane chamber integrated flow-electrode electrochemical system,Water Research, 202, 2021, 17423
6.Yang Zong, Hua Zhang, Xiaomeng Zhang, Wen Liu, Longqian Xu,Deli Wu, High-valent cobalt-oxo species triggers hydroxyl radical for collaborative environmental decontamination,Applied Catalysis B: Environmental, 300, 2022, 120722
7.Longqian Xu, Yunfeng Mao, Yang Zong,Deli Wu, Scale-up desalination: membrane-current collector assembly in flow-electrode capacitive deionization system,Water Research, 202,2021, 116782
8.Yang Zong, Hua Zhang, Yufei Shao, Wenjie Ji, Yunqiao Zeng, Longqian Xu,Deli Wu, Surface-mediated periodate activation by nano zero-valent iron for the enhanced abatement of organic contaminants,Journal of Hazardous Materials, 423, 2022, 126991
9.Bing Zhang, Longqian Xu, Zhenyu Zhao, Shuai Peng, Chao Yu, Xiaomeng Zhang, Yang Zong,Deli Wu, Enhanced phosphate removal by nano-lanthanum hydroxide embedded silica aerogel composites: Superior performance and insights into specific adsorption mechanism,Separation and Purification Technology, 285, 2022, 120365
10.Hongping He, Jiaxin Wang, Xunchang Fei,Deli Wu, Sequestration of free and chelated Ni(II) by structural Fe(II): Performance and mechanisms,Environmental Pollution, 292, 2022, 118374
11.Longqian Xu, Chao Yu, Jiaming Zhang, Ren Ding, Yunfeng Mao, Yang Zong,Deli Wu, Selective recovery of formic acid from wastewater using an ion-capture electrochemical system integrated with a liquid-membrane chamber,Chemical Engineering Journal, 425, 2021, 131429
12.Yang Zong, Hua Zhang, Xiaomeng Zhang, Yufei Shao, Yunqiao Zeng, Wenjie Ji, Longqian Xu,Deli Wu, Highly selective oxidation of organic contaminants in the RuIII-activated peroxymonosulfate process: The dominance of RuVO species,Chemosphere, 285, 2021, 131544
13.Xiaomeng Zhang, Yang Zong, Longqian Xu, Yunfeng Mao,Deli Wu, Enhanced abiotic integrated polyphenol-Maillard humification by Mg/Fe layered double hydroxide (LDH): Role of Fe(III)-polyphenol complexation,Chemical Engineering Journal, 425, 2021, 130521
14.Chao Yu, Longqian Xu, Yunfeng Mao, Yang Zong,Deli Wu, Efficient recovery of carboxylates from the effluents treated by advanced oxidation processes using flow-electrode capacitive deionization in short-circuited closed-cycle operation,Separation and Purification Technology, 275, 2021, 119151
15.Longqian Xu, Chao Yu, Yunfeng Mao, Yang Zong, Bing Zhang, Huaqiang Chu,Deli Wu. Can Flow-Electrode Capacitive Deionization Become a New in-Situ Soil Remediation Technology for Heavy Metal Removal?Journal of Hazardous Materials. 2021, 402, 123568
16.Yunfeng Mao, Vikram Reddy Ardham, Longqian Xu, Pengyi Cui,Deli Wu, Insight into electrosorption behavior of monovalent ions and their selectivity in capacitive deionization: An atomic level study by molecular dynamics simulation,Chemical Engineering Journal, 415, 2021, 128920
17.Deli Wu, Shiyu Tian, Jiajun Long, Shuai Peng, Longqian Xu, Wen Sun, Huaqiang Chu, Remarkable phosphate recovery from wastewater by a novel Ca/Fe composite: Synergistic effects of crystal structure and abundant oxygen-vacancies,Chemosphere, 266, 2021, 129102
18.Longqian Xu, Yu Xie, Yang Zong, Yunfeng Mao, Bing Zhang, Huaqiang Chu,Deli Wu. Formic Acid Recovery from EDTA Wastewater Using Coupled Ozonation and Flow-Electrode Capacitive Deionization ( Ozo/FCDI ): Performance Assessment at High Cell Voltage.Separation and Purification Technology. 2021, 254, 117613
19.Longqian Xu, Chao Yu, Shiyu Tian, Yunfeng Mao, Yang Zong, Xiaomeng Zhang, Bing Zhang, Changyong Zhang,Deli Wu. Selective Recovery of Phosphorus from Synthetic Urine Using Flow-Electrode Capacitive Deionization (FCDI)-Based Technology.ACS ES&T Water2021 1 (1), 175-184
20.Longqian Xu, Kaili Yan, Yunfeng Mao,Deli Wu. Enhancing the dioxygen activation for arsenic removal by Cu0 nano-shell-decorated nZVI: Synergistic effects and mechanisms.Chemical Engineering Journal, 2020, 384, 123295.
21.Yang Zong, Yunfeng Mao, Longqian Xu,Deli Wu. Non-selective degradation of organic pollutants via dioxygen activation induced by Fe(II)-tetrapolyphosphate complexes: Identification of reactive oxidant and kinetic modeling.Chemical Engineering Journal. 2020, 398, 125603
22.Yufan Chen, Yong Feng, Huaqiang Chu,Deli Wu, Yalei Zhang. Cu(II)-enhanced activation of molecular oxygen using Fe(II): Factors affecting the yield of oxidants.Chemosphere, 2019, 221, 383-391
23.Longqian Xu, Xiaojun Xu,Deli Wu. Initial dissolved oxygen-adjusted electrochemical generation of sulfate green rust for cadmium removal using a closed-atmosphere Fe–electrocoagulation system.Chemical Engineering Journal, 2019, 359,1411-141
24.Yong Feng, Weihua Qing, Lingjun Kong, Hailong Li,Deli Wu, Yiang Fan, Po-Heng Lee, Kaimin Shih. Factors and mechanisms that influence the reactivity of trivalent copper A novel oxidant for selective degradation of antibiotics.Water Research, 2019, 149, 43473
25.Deli Wu, Yang Zong, Zeyuan Tian, Binbin Shao. Role of reactive oxygen species in As(III) oxidation by carbonate structural Fe(II): A surface-mediated pathway.Chemical Engineering Journal, 2019, 368, 980-998
26.Yu Xie, Lin Gu, Shun Mao,Deli Wu, Jinhong Fan,. The Role of Structural Elements and Its Oxidative Products on the Surface of Ferrous Sulfide in Reducing the Electron-Withdrawing Groups of Tetracycline.Chemical Engineering Journal. 2019, 378, 122195
27.Yong Feng, Po-Heng Lee,Deli Wu, Kaimin Shih. Rapid Selective Circumneutral Degradation of Phenolic Pollutants Using Peroxymonosulfate-Iodide Metal-Free Oxidation: Role of Iodine Atoms.Environmental Science & Technology, 2017, 51: 2312-2320
28.Feng Yong,Wu Deli, Deng Yu, Zhang Tong, Shi Kaimin . Sulfate Radical-Mediated Degradation of Sulfadiazine by CuFeO2 Rhombohedral Crystal-Catalyzed Peroxymonosulfate: Synergistic Effects and Mechanisms .Environmental Science and Technology. 2016, 50(6): 3119-3127
29.Deli Wu, Shuhan Peng, Kaili Yan, Binbin Shao, Yong Feng, and Yalei Zhang.Enhanced As(III) Sequestration Using Sulfide-Modified Nano-Scale Zero-Valent Iron with a Characteristic Core–Shell Structure: Sulfidation and As Distribution .ACS Sustainable Chemistry & Engineering, 2018, 6(3): 3039-3048
30.Jinhong Fan, Lin Gu,Deli Wu, Zhigang Liu,Mackinawite (FeS) activation of persulfate for the degradation of p-chloroaniline: Surface reaction mechanism and sulfur-mediated cycling of iron species,Chemical Engineering Journal, 2018, 333: 657-664
31.Peng Shuhan, Feng Yong, Liu Ying,Wu Deli. Applicability study on the degradation of acetaminophen via an H2O2/PDS-based advanced oxidation process using pyrite .Chemosphere, 2018, 212: 438-446
32.Zhao Linghui, Chen Yufan, Feng Yong,Wu Deli. Oxidation of acetaminophen by Green rust coupled with Cu(II) via dioxygen activation: The role of various interlayer anions (CO32-, SO42-, Cl-).Chemical Engineering Journal.2018, 350: 930-938
33.Shao Binbin, Chen Yufan,Wu Deli, Dai Chaomeng, Zhang Yalei .Mineral transformation of structural Fe(II) hydroxides with O2, Cu(II), Cr(VI) and NO2− for enhanced arsenite sequestration .Chemical Engineering Journal, 2017, 311: 247-254
34.Yong Feng, Po-Heng Lee,Deli Wu, Kaimin Shih. Surface-bound sulfate radical-dominated degradation of 1,4-dioxane by alumina-supported palladium (Pd/Al2O3) catalyzed peroxymonosulfate.Water Research, 2017, 120: 12–21.
35.He H, Liu Y,Wu D, Guan X, Zhang Y. Ozonation of dimethyl phthalate catalyzed by highly active CuxO-Fe3O4 nanoparticles prepared with zero-valent iron as the innovative precursor.Environmental Pollution, 2017, 227: 73-82.
36.He Hongping,Wu Deli, Zhao Linghui, Luo Cong, Dai Chaomeng, Zhang Yalei . Sequestration of chelated copper by structural Fe(II): Reductive decomplexation and transformation of CuII-EDTA .Journal of Hazardous Materials, 2016, 309: 116-125
37.Deli Wu, Ying Liu, Hongping He, Yaler Zhang . Magnetic pyrite cinder as an efficient heterogenous ozonation catalyst and synergetic effect of deposited Ce .Chemosphere, 2016, 155: 127-134
38.He, Hongping,Wu, Deli, Wang, Quanming, Luo, Cong, Duan, Ning . Sequestration of hexavalent chromium by Fe(II)/Fe(III) hydroxides: Structural Fe(II) reactivity and PO43- effect .Chemical Engineering Journal, 2016, 283: 948-955
39.Wu Deli, Chen Yufan, Zhang Zhiyong, Feng Yong, Liu Yanxia, Fan Jinhong, Zhang Yalei . Enhanced oxidation of chloramphenicol by GLDA-driven pyrite induced heterogeneous Fenton-like reactions at alkaline condition .Chemical Engineering Journal, 2016,294: 49-57
40.Deli Wu, Binbin Shao, Minyu Fu, Cong Luo, Zhigang Liu. Denitrification of nitrite by ferrous hydroxy complex: Effects on nitrous oxide and ammonium formation.Chemical Engineering Journal, 2015, 279: 149-155
41.Wu Deli, Chen Yufan, Zhang Yalei, Feng Yong, Shih Kaimin . Ferric iron enhanced chloramphenicol oxidation in pyrite(FeS2) induced Fenton-like reactions .Separation and Purification Technology, 2015, 154(5): 60-67
42.Cong Luo, Zhe Chen,Deli Wu, Luming Ma. Electrochemical reductive degradation of chlorobenzene using galvanically replaced Pd/Fe nanoscale particles.Chemical Engineering Journal, 2014, 241: 376-383
43.Chen Zhe, Wang Zi, ,Wu DeliMa Luming. Electrochemical study of nitrobenzene reduction on galvanically replaced nanoscale Fe/Au particles.Journal of Hazardous Materials. 2011, 197: 424-429
44.Yongli Jiao, Cuicui Qiu, Lihui Huang, Houyi Ma, Luming Ma,Deli Wu. Reductive dechlorinaton of carbon tetrachloride by zero-valent iron and related iron corrosion,Applied Catalysis B: Environmental, 2009, 91 (1-2): 434-440
发明专利
[1]吴德礼,马鲁铭,王红武.表面改性催化铁还原脱氯处理水中含氯有机物的方法(Zl200610027338.1)
[2]吴德礼,马鲁铭,王红武. CFP催化还原体系快速还原去除水体中氯代有机污染物的方法(ZL200610027339.6)
[3]吴德礼,段冬,马鲁铭.黄铁矿烧渣催化H2O2氧化处理难降解污染物的方法(ZL200910197385.4)
[4]吴德礼,冯勇,马鲁铭.多羟基结构态亚铁化合物的制备及用于废水还原预处理(ZL201010553595.5)
[5]吴德礼,冯勇,王权民.强化多羟基亚铁化合物处理废水的方法(ZL201210067117.2)
[6]吴德礼,冯勇,王权民,马鲁铭.利用新生态亚铁还原预处理工业废水的方法(ZL201210070040.4)
[7]吴德礼,王权民,冯勇,马鲁铭.亚铁还原与催化氧化协同强化废水生物处理工艺(ZL201210074135.3)
[8]吴德礼,王权民,冯勇,马鲁铭.多羟基亚铁络合物还原体系及其制备方法和应用(ZL201210081751.1)
[9]吴德礼,冯勇,王权民,马鲁铭.钯催化多羟基亚铁还原去除水中污染物的方法(ZL201210085903.5)
[10]吴德礼,章智勇.天然硫铁矿催化H2O2氧化深度处理工业废水的方法(ZL201310732115.5)
[11]吴德礼,何宏平,张亚雷.一种利用黄铁矿烧渣催化臭氧氧化处理废水的方法(ZL201410046854.3)
[12]吴德礼,赵凌晖,章智勇.修复地下水纳米Pd/Fe羟基氧化物复合材料制备方法(ZL201510129993.7)
[13]吴德礼,章智勇.一种提高黄铁矿催化类Fenton持续反应活性的方法(ZL201510133185.8)
[14]吴德礼,张亚雷,刘燕夏.一种铁硫多相类芬顿催化剂的制备方法及应用(ZL201510928121.7)
[15]吴德礼,刘莹,何宏平.一种磁性纳米CuxO-Fe2O3臭氧催化剂的制备方法及其应用(ZL201610229363.1)
[16]吴德礼,田泽源,张亚雷,马鲁铭.一种磁性铁基材料还原破络去除络合态重金属的方法(ZL201710216650.3)
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